Pendlebury, M. H. published the artcileBarriers to rotation about carbon-nitrogen bonds. I. Rotation about the carbon-nitrogen bond in mono-, di-, and trifluoroacetamide, and deuterium isotope effects upon fluorine-19 shielding, Synthetic Route of 359-38-6, the main research area is fluoroacetamide NMR; acetamide fluoro NMR; rotation carbon nitrogen fluoroacetamide; fluorine shielding fluoroacetamide.
The 19F NMR spectra of FCH2CONH2 (I) and F2CHCONH2 (II) are used to derive the activation parameters for rotation about the C-N bond; it is not possible to obtain useful results for CF3CO2NH2 (III). A total line shape anal. is used. Unusually large D isotope effects on the shielding of the 19F nucleus were observed for N-deuterated derivatives The magnitude of the isotope effect is different for I-III, and in the mono-deuterated species the isotope effect is different for cis and trans rotational isomers.
Organic Magnetic Resonance published new progress about Bond. 359-38-6 belongs to class amides-buliding-blocks, name is 2,2-Difluoroacetamide, and the molecular formula is C2H3F2NO, Synthetic Route of 359-38-6.
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics