Meng, Nannan published the artcileElectrosynthesis of formamide from methanol and ammonia under ambient conditions, HPLC of Formula: 123-39-7, the main research area is formamide electrochem oxidation optical property density functional theory.
Electrochem. conversion of abundant carbon- and nitrogen-containing small mols. into high-valued organonitrogen compounds is alluring to reducing current dependence on fossil energy. Here we report a single-cell electrochem. oxidation approach to transform methanol and ammonia into formamide under ambient conditions over Pt electrocatalyst that provides 74.26% selectivity from methanol to formamide and a Faradaic efficiency of 40.39% at 100 mA cm-2 c.d., gaining an economic advantage over conventional manufacturing based on techno-economic anal. A 46-h continuous test performed in the flow cell shows no performance decay. The combined results of in situ experiments and theor. simulations unveil the C-N bond formation mechanism via nucleophilic attack of NH3 on an aldehyde-like intermediate derived from methanol electrooxidation This work offers a way to synthesize formamide via C-N coupling and can be extended to substantially synthesize other value-added organonitrogen chems. (e.g., acetamide, propenamide, formyl methylamine).
Nature Communications published new progress about Binding energy. 123-39-7 belongs to class amides-buliding-blocks, name is N-Methylformamide, and the molecular formula is C2H5NO, HPLC of Formula: 123-39-7.
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics