Schaad, David R. published the artcileReactions of amides with zerovalent and divalent palladium and platinum complexes, Quality Control of 359-38-6, the main research area is methylplatinum photosubstitution amide triflamide trifluoroacetamide; methylpalladium photosubstitution amide triflamide trifluoroacetamide; palladium zerovalent divalent amide; platinum zerovalent divalent amide; hydroamination catalysis amidepalladium amideplatinum.
The reactions of amides (RCONH2 and CF3SO2NH2) with L2Pd(CH3)2 and L2Pt(CH3)2 and with transient L2Pt(0) to yield new complexes containing palladium- and platinum-amido nitrogen bonds are reported. Photolysis of Pt(C2O4)(PEt3)2 in the presence of amide generates products of the type trans-PtH(HNR)(PEt3)2 [R = SO2CF3 (1a), COCF3 (1b)]. Reaction of amides with trans-PtH(CH3)(PEt3)2 (2), cis-PdMe2(PEt3)2 (3), cis-PtMe2(PEt3)2 (4), PdMe2(dcpe) (5), PdMe2(dmpe) (6), and PtMe2(COD) (7) produces 1a,b, trans-PdMe(HNR)(PEt3)2 [R = SO2CF3 (3a), COCF3 (3b), COCF2H (3c), COPh (3d)], PtMe(HNR)(PEt3)2 [R = SO2CF3 (4a), COCF3 (4b)], PdMe(HNR)(dcpe) [R = SO2CF3 (5a), COCF3 (5b), COPh (5c)], PdMe(HNSO2CF3)(dmpe) (6a), and PtMe(HNR)(COD) [R = SO2CF3 (7a), COCF3 (7b)], resp. The stereochem. and topologies of the new compounds are established by multinuclear NMR spectroscopy. The relevance of these reactions to hydroaminium catalysis is discussed.
Organometallics published new progress about Coordinative photosubstitution reaction. 359-38-6 belongs to class amides-buliding-blocks, name is 2,2-Difluoroacetamide, and the molecular formula is C2H3F2NO, Quality Control of 359-38-6.
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics