Mkhonazi, Blessing D. published the artcilePalladium-Catalysed Reductive Aminocarbonylation of Aryl Bromides and Iodides with Nitroarenes, Application of 4-Methoxy-N-phenylbenzamide, the main research area is aryl amide preparation; nitroarene bromide aryl iodide palladium catalyzed reductive aminocarbonylation.
Herein, a palladium-catalyzed reductive aminocarbonylation of aryl bromides and iodides with nitroarenes to afford the resp. amides RC(O)NHR1 [R = Ph, 4-MeOC6H4, 3,5-diMeC6H3, etc.; R1 = Ph, 4-MeC6H4, 2-ClC6H4, etc.] was reported. The developed protocol employed Mo(CO)6 as a carbonyl source and a combination of Zn and TMSCl as co-reducing agents. For most substrates, the anticipated amide products were obtained in modest to high amide product yields.
SynOpen published new progress about Aminocarbonylation (reductive). 7465-88-5 belongs to class amides-buliding-blocks, name is 4-Methoxy-N-phenylbenzamide, and the molecular formula is C14H13NO2, Application of 4-Methoxy-N-phenylbenzamide.
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics