Bi, Wen-Zhu published the artcileVisible-light-promoted synthesis of secondary and tertiary thiocarbamates from thiosulfonates and N-substituted formamides, Formula: C2H5NO, the main research area is secondary thiocarbamate tertiary preparation; thiosulfonate formamide thiolation rhodamine B photocatalyst.
A general visible-light-promoted metal-free synthesis of secondary and tertiary thiocarbamates RSC(O)NR1R2 [R = Ph, 4-MeC6H4, Bn, etc., R1 = Me, iso-Pr, cyclohexyl, etc., R2 = H, Me, Et, n-Pr, iso-Pr, (CH2)3CH3, R1R2 = (CH2)5, (CH2)2O(CH2)2] starting from thiosulfonates and N-substituted formamides was developed. By employing rhodamine B as a photocatalyst and tert-Bu hydroperoxide (TBHP) as an oxidant, a wide scope of thiocarbamates could be obtained through direct thiolation of acyl C-H bonds under irradiation of blue light at room temperature for 12 h.
Organic & Biomolecular Chemistry published new progress about Formamides Role: RCT (Reactant), RACT (Reactant or Reagent). 123-39-7 belongs to class amides-buliding-blocks, name is N-Methylformamide, and the molecular formula is C2H5NO, Formula: C2H5NO.
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics