Fan, Pei published the artcileNickel/Photo-Cocatalyzed C(sp2)-H Allylation of Aldehydes and Formamides, Formula: C2H5NO, the main research area is unsaturated ketone amide preparation stereoselective; aldehyde formamide allyl acetate alc allylation nickel photocatalyst.
Herein, a nickel/photo-cocatalyzed C(sp2)-H allylation of aldehydes and formamides wherein both allyl acetates and allyl alcs. can be used as the allylating agents is reported. In this reaction, radical-type umpolung of the formyl moiety is enabled by tetrabutylammonium decatungstate as a hydrogen-atom-transfer photocatalyst, whereas nickel serves to cleave the C-O bond of allyl acetates or allyl alcs. The synergistic effect of these two catalysts provides new access to various β,γ-unsaturated ketones and amides with high selectivities.
Organic Letters published new progress about Acetates Role: RCT (Reactant), RACT (Reactant or Reagent) (allyl). 123-39-7 belongs to class amides-buliding-blocks, name is N-Methylformamide, and the molecular formula is C2H5NO, Formula: C2H5NO.
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics