Cobos, Ana published the artcileSolid-liquid equilibria and excess enthalpies in binary mixtures of acetophenone with some aliphatic amides, Synthetic Route of 123-39-7, the main research area is acetophenone aliphatic amide solid liquid equilibrium excess enthalpy.
Solid-liquid equilibrium for the binary systems of acetophenone and {N-methylformamide, or N,N-dimethylformamide, or N,N-dimethylacetamide, or N-methyl-2-pyrrolidone} were determined by the cloud-point and DSC techniques. For the same systems, excess enthalpies were measured at 293.15 K and 308.15 K by the titration calorimetry. Both types of data were correlated by the Redlich-Kister equation. The description of the solid-liquid equilibrium incorporated measured excess enthalpies. The results of the prediction performed by the modified UNIFAC model were compared with the exptl. data. The observed trends and differences between systems were discussed.
Journal of Molecular Liquids published new progress about Binary mixtures. 123-39-7 belongs to class amides-buliding-blocks, name is N-Methylformamide, and the molecular formula is C2H5NO, Synthetic Route of 123-39-7.
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics