On February 5, 2021, Das, Saikat; Murugesan, Kathiravan; Villegas Rodriguez, Gonzalo J.; Kaur, Jaspreet; Barham, Joshua P.; Savateev, Aleksandr; Antonietti, Markus; Koenig, Burkhard published an article.HPLC of Formula: 685-91-6 The title of the article was Photocatalytic (Het)arylation of C(sp3)-H Bonds with Carbon Nitride. And the article contained the following:
Mesoporous graphitic carbon nitride(mpg-CN)as a heterogeneous organic semiconductor photocatalyst for direct arylation of sp3 C-H bonds in combination with nickel catalysis are reported. This protocol has a broad synthetic scope (>70 examples including late-stage functionalization of drugs and agrochems.), was operationally simple, and shows high chemo- and regioselectivities. Facile separation and recycling of the mpg-CN catalyst in combination with its low preparation cost, innate photochem. stability, and low toxicity are beneficial features overcoming typical shortcomings of homogeneous photocatalysis. Detailed mechanistic investigations and kinetic studies indicate that an unprecedented energy-transfer process (EnT) from the organic semiconductor to the nickel complex was operated. The experimental process involved the reaction of N,N-Diethylacetamide(cas: 685-91-6).HPLC of Formula: 685-91-6
The Article related to alkylamide aryl halide carbon nitride regioselective chemoselective arylation photochem, aryl methylalkylamide preparation, General Organic Chemistry: Synthetic Methods and other aspects.HPLC of Formula: 685-91-6
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics