Yao, Wubing; Yang, Jianguo; Hao, Feiyue published an article in 2020, the title of the article was Ru-Catalyzed Selective C(sp3)-H Monoborylation of Amides and Esters.Reference of N,N-Diethylacetamide And the article contains the following content:
A ruthenium-catalyzed method has been developed for the C(sp3)-H monoborylation of various unactivated alkyl and aryl amides and challenging esters, with a low-cost and bench-stable boron source, providing boronates with exclusive selectivity, high efficiency, and high turnover number (up to 8900). This novel strategy may offer a versatile and environmentally friendly alternative to current methods for selective C(sp3)-H borylation that employ even more expensive metals, such as iridium and rhodium. The experimental process involved the reaction of N,N-Diethylacetamide(cas: 685-91-6).Reference of N,N-Diethylacetamide
The Article related to green chem ruthenium catalyst selective borylation amide ester, boronic ester preparation green chem, c−h activation, amides, borylation, ester, ruthenium, Organometallic and Organometalloidal Compounds: Boron Compounds and other aspects.Reference of N,N-Diethylacetamide
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics