On April 20, 2018, Zhou, Xibing; Zhang, Guoying; Gao, Bao; Huang, Hanmin published an article.Reference of N,N-Diethylacetamide The title of the article was Palladium-Catalyzed Hydrocarbonylative C-N Coupling of Alkenes with Amides. And the article contained the following:
Terminal alkenes such as styrene and norbornene underwent regioselective hydrocarbonylation and acyl metathesis reactions with amides such as DMF using NH4Cl or N-methylpyrrolidine hydrochloride as additive under 10 atm. CO pressure at 120° in the presence of either Pd(Pt-Bu3)2 or Pd(MeCN)2Cl2 and Xantphos to yield amides such as PhCHMeCONMe2 or PhCH2CH2CONMe2, resp. N-alkenylamides underwent intramol. hydrocarbonylation and acyl metathesis reactions to yield lactams. Use of NMP·DCl as additive yielded partially deuterated amides. The experimental process involved the reaction of N,N-Diethylacetamide(cas: 685-91-6).Reference of N,N-Diethylacetamide
The Article related to amide regioselective preparation, palladium catalyst regioselective hydrocarbonylation metathesis alkene amide, Aliphatic Compounds: Amides, Amidines, Imidic Esters, Hydrazides, and Hydrazonic Esters and other aspects.Reference of N,N-Diethylacetamide
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics