Jain, Preeti; Kumar, Anil published an article in 2018, the title of the article was Structural Elucidation of the Binary Mixtures of [EMIM][BF4] and [BMIM][BF4] in Ethyl-Substituted Solvents by Isothermal Titration Calorimeter.Category: amides-buliding-blocks And the article contains the following content:
In order to address the issue whether both ionic liquids and solvents influence the enthalpy of their solutions, highly accurate excess partial molar enthalpy, HILE values have been measured using Isothermal Titration Calorimeter (ITC). Therefore, thermodn. behavior has been observed in the mixtures containing ionic liquids It essentially depends on the mol. structure of the constituents of the mixture The hydrogen bonding between ionic liquids and ethyl-substituted solvents (2-ethoxyethanol, ethylene glycol, diethylamine, Et acetate and N,N- diethylacetamide) may lead to strong ion-solvent interactions. In the present study, an effort has been made to quantify various interactions between ionic liquid and solvent, based on the HILE values. Linear solvation free relation shows dependence of limiting excess partial molar enthalpies, HILE,∞ upon the solvent properties. Structural orientation of solvent mols. and ionic liquids also described by the HILE,∞ values. The ion-ion, ion-solvent interactions have also been investigated in terms of the enthalpic interaction parameters, HIL-ILE and relative apparent molar enthalpy, φL of ionic liquid-ethyl-substituted solvent systems. The experimental process involved the reaction of N,N-Diethylacetamide(cas: 685-91-6).Category: amides-buliding-blocks
The Article related to solvent ionic liquid binary mixture structural elucidation, Thermodynamics, Thermochemistry, and Thermal Properties: Thermochemical Properties and other aspects.Category: amides-buliding-blocks
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics