Vala, Anand et al. published their research in Synlett in 2022 |CAS: 102-07-8

The Article related to indole carboxamide preparation chemoselective, dioxazolone indole carboxamidation, Heterocyclic Compounds (One Hetero Atom): Indoles, Indolizines, Carbazoles, and Other Arenopyrroles and other aspects.Synthetic Route of 102-07-8

On April 30, 2022, Vala, Anand; Parmar, Deepa; Rayani, Rahul; Kusurkar, Rakesh; Guduru, Ramakrishna; Kaneriya, Uttam; Gondaliya, Uday; Parmar, Nirali; Soni, Jigar Y. published an article.Synthetic Route of 102-07-8 The title of the article was 1,4,2-Dioxazol-5-ones as Isocyanate Equivalents: Chemoselective Non-Metal-Catalyzed Carboxamidation of Indoles. And the article contained the following:

1,4,2-Dioxazol-5-ones are known to undergo decarboxylation under thermal conditions followed by Lossen’s rearrangement to give isocyanates. Described herein is the in situ trapping of the isocyanates by indoles to give indole-3-carboxamides in good to excellent yields. The experimental process involved the reaction of 1,3-Diphenylurea(cas: 102-07-8).Synthetic Route of 102-07-8

The Article related to indole carboxamide preparation chemoselective, dioxazolone indole carboxamidation, Heterocyclic Compounds (One Hetero Atom): Indoles, Indolizines, Carbazoles, and Other Arenopyrroles and other aspects.Synthetic Route of 102-07-8

Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics