On July 18, 2009, Martins, Jose E. D.; Wills, Martin published an article.Electric Literature of 167316-28-1 The title of the article was Ir(III) complexes of diamine ligands for asymmetric ketone hydrogenation. And the article contained the following:
The use of a combination of IrCl3 with a series of ligands derived from the C2-sym. diamine diphenylethanediamine (DPEN) forms a catalyst capable of the asym. hydrogenation of ketones in up to 85% ee. The experimental process involved the reaction of N-[(1S,2S)-2-Amino-1,2-diphenylethyl]-1,1,1-trifluoromethanesulfonamide(cas: 167316-28-1).Electric Literature of 167316-28-1
The Article related to arylalkanol asym preparation, arylketone asym hydrogenation iridium chiral diamine, chiral diaminepreparation iridium asym hydrogenation catalyst, diamine sulfonylation reductive amination and other aspects.Electric Literature of 167316-28-1
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics