Elliott, Rory; Ryan, Aoife A.; Aggarwal, Aviral; Zhu, Nianyong; Steuber, Friedrich W.; Senge, Mathias O.; Schmitt, Wolfgang published an article in 2021, the title of the article was 2D porphyrinic metal-organic frameworks featuring rod-shaped secondary building units.Application In Synthesis of N,N-Diethylacetamide And the article contains the following content:
Metal-organic frameworks (MOFs) encompass a rapidly expanding class of materials with diverse potential applications including gas storage, mol. separation, sensing and catalysis. So-called ‘rod MOFs’, which comprise infinitely extended 1D secondary building units (SBUs), represent an underexplored subclass of MOF. Further, porphyrins are considered privileged ligands for MOF synthesis due to their tunable redox and photophys. properties. In this study, the CuII complex of 5,15-bis(4-carboxyphenyl)-10,20-diphenylporphyrin (H2L-CuII, where H2 refers to the ligand’s carboxyl H atoms) is used to prepare two new 2D porphyrinic rod MOFs PROD-1 and PROD-2. Single-crystal X-ray anal. reveals that these frameworks feature 1D MnII- or CoII-based rod-like SBUs that are coordinated by labile solvent mols. and photoactive porphyrin moieties. Both materials were characterised using IR (IR) spectroscopy, powder X-ray diffraction (PXRD) spectroscopy and thermogravimetric anal. (TGA). The structural attributes of PROD-1 and PROD-2 render them promising materials for future photocatalytic investigations. The experimental process involved the reaction of N,N-Diethylacetamide(cas: 685-91-6).Application In Synthesis of N,N-Diethylacetamide
The Article related to porphyrinic metal organic framework secondary building unit, 2d mof, 2d materials, mof, porphyrin mof, porphyrinoids, coordination chemistry, metal-organic framework, rod mof and other aspects.Application In Synthesis of N,N-Diethylacetamide
Referemce:
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