Zhao, Xiang; Nguyen, Edward T.; Hong, Anh N.; Feng, Pingyun; Bu, Xianhui published an article in 2018, the title of the article was Chiral Isocamphoric Acid: Founding a Large Family of Homochiral Porous Materials.Safety of N,N-Diethylacetamide And the article contains the following content:
Homochiral metal-organic frameworks (MOFs) are an important class of chiral solids with potential applications in chiral recognition; however, relatively few are available. Of great importance is the availability of low-cost, racemization-resistant, and versatile enantiopure building blocks. Among chiral building blocks, D-camphoric acid is highly prolific, yet, its trans-isomer, L-isocamphoric acid, has remained unknown in the entire field of solid-state materials. Its rich yet totally untapped synthetic and structural chem. has now been studied through the synthesis of a large family of homochiral metal isocamphorates. The 1st observation of diastereoisomerism in isostructural MOFs is presented. Isocamphorate has a powerful ability to create framework topologies unexpected from common inorganic building blocks, and isocamphoric acid should allow access to hundreds of new homochiral materials. The experimental process involved the reaction of N,N-Diethylacetamide(cas: 685-91-6).Safety of N,N-Diethylacetamide
The Article related to chiral isocamphorate preparation homochiral porous material, transition metal isocamphorate camphorate mof preparation, crystal structure magnesium cobalt copper isocamphorate camphorate mof, camphoric acid, chiral ligands, homochiral porous materials, isocamphoric acid, metal-organic frameworks and other aspects.Safety of N,N-Diethylacetamide
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics