Mao, Yu; Liu, Yeqing; Yu, Lei; Ni, Shengyang; Wang, Yi; Pan, Yi published an article in 2021, the title of the article was Uranyl-catalysed C-H alkynylation and olefination.Product Details of 685-91-6 And the article contains the following content:
A strategy to utilize uranyl for direct alkynylation and olefination of amides was described. The uranyl cation (UO22+) was identified as a highly oxidizing agent to abstract hydrogen atoms from C-H bonds for the formation of carbon-centered radicals. The photoexcitation of uranyl cations provides a range of carbon-centered radicals via hydrogen atom transfer, which can be successfully applied in cross-coupling reactions with a broad range of alkynyl and alkenyl bromides. The experimental process involved the reaction of N,N-Diethylacetamide(cas: 685-91-6).Product Details of 685-91-6
The Article related to amide bromoalkyne uranyl catalyst regioselective alkynylation, alkynyl amide preparation, alkenylbromide amide uranyl catalyst regioselective alkenylation, alkenyl amide preparation, allylbromide amide uranyl catalyst regioselective allylation, allyl amide preparation and other aspects.Product Details of 685-91-6
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics