In 2019,Tetrahedron included an article by Zhou, Tianyi; Ringbeck, Benedikt; Schebb, Nils Helge; Scherkenbeck, Juergen. Computed Properties of C11H24N2O. The article was titled 《Isolation, total synthesis and quantification of caffeoylisocitric acid, a characteristic ingredient of the superfood amaranth》. The information in the text is summarized as follows:
Amaranth is regarded as a new “”super-vegetable”” in western countries, albeit it is consumed for centuries in Africa and Asia. In addition to common carotenoids, flavonoids and polyphenols, caffeoylisocitric acid has been described as amaranth type-specific secondary metabolite. Remarkably, nothing is known on biol. effects of this specific polyphenol. Here we detail a concise, diastereoselective synthesis of caffeoylisocitric acid (I), deuterium-labeling studies and a quant. determination of the caffeoylisocitric acid content of three different amaranth types.tert-Butyl N,N’-diisopropylcarbamimidate(cas: 71432-55-8Computed Properties of C11H24N2O) was used in this study.
tert-Butyl N,N’-diisopropylcarbamimidate(cas: 71432-55-8) belongs to anime. Primary amines having a tertiary alkyl group (R3CNH2) are difficult to prepare with most methods but are made industrially by the Ritter reaction. In this method a tertiary alcohol reacts with hydrogen cyanide (HCN) in the presence of a concentrated strong acid; a formamide, RNH―CHO, is formed first, which then undergoes hydrolysis.Computed Properties of C11H24N2O
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics