In 2019,Heterocycles included an article by Tanimoto, Iku; Kawai, Kentaro; Sato, Akane; Yoshino, Tatsuhiko; Matsunaga, Shigeki. Recommanded Product: N-Methoxy-N-methylacetamide. The article was titled 《One-step synthesis of 4H-3,1-benzoxazin-4-ones from Weinreb amides and 1,4,2-dioxazol-5-ones via cobalt-catalyzed C-H bond activation》. The information in the text is summarized as follows:
A one-step synthesis of 4H-3,1-benzoxazin-4-ones e.g., 2-phenyl-4H-benzo[d][1,3]oxazin-4-one from readily available Weinreb amides I (R = t-Bu, Ph, thiophen-2-yl, etc.) and 1,4,2-dioxazol-5-ones e.g., N-methoxy-N-methylbenzamide under Cp*Co(III) catalysis is described. The reactions proceeded in moderate to good yields with high functional group compatibility. After reading the article, we found that the author used N-Methoxy-N-methylacetamide(cas: 78191-00-1Recommanded Product: N-Methoxy-N-methylacetamide)
N-Methoxy-N-methylacetamide(cas: 78191-00-1) belongs to anime. Aniline, ethanolamines, and several other amines are major industrial commodities used in making rubber, dyes, pharmaceuticals, and synthetic resins and fibres and for a host of other applications. Most of the numerous methods for the preparation of amines may be broadly divided into two groups: (1) chemical reduction (replacement of oxygen with hydrogen atoms in the molecule) of members of several other classes of organic nitrogen compounds and (2) reactions of ammonia or amines with organic compounds.Recommanded Product: N-Methoxy-N-methylacetamide
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics