In 2017,Ghatak, Tapas; Fridman, Natalia; Eisen, Moris S. published 《Actinide Complexes Possessing Six-Membered N-Heterocyclic Iminato Moieties: Synthesis and Reactivity》.Organometallics published the findings.Product Details of 71432-55-8 The information in the text is summarized as follows:
A novel class of ligand systems possessing a six-membered N-heterocyclic iminato [perimidin-2-iminato (PrRN where R = iso-Pr, cycloheptyl)] moiety is introduced. The complexation of these ligands with early actinides (An = Th and U) results in powerful catalysts [(PrRN)AnN{(SiMe3)2}3] (3-6)for exigent insertion of alcs. into carbodiimides to produce the corresponding isoureas in short reaction times with excellent yields. Exptl., thermodn., and kinetic data as well as the results of stoichiometric reactions provide cumulative evidence that support a plausible mechanism for the reaction.tert-Butyl N,N’-diisopropylcarbamimidate(cas: 71432-55-8Product Details of 71432-55-8) was used in this study.
tert-Butyl N,N’-diisopropylcarbamimidate(cas: 71432-55-8) belongs to anime. Reduction of nitro compounds, RNO2, by hydrogen or other reducing agents produces primary amines cleanly (i.e., without a mixture of products), but the method is mostly used for aromatic amines because of the limited availability of aliphatic nitro compounds. Reduction of nitriles and oximes (R2C=NOH) also yields primary amines.Product Details of 71432-55-8
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics