In 2015,CrystEngComm included an article by Forgan, Ross S.; Marshall, Ross J.; Struckmann, Mona; Bleine, Aurore B.; Long, De-Liang; Bernini, Maria C.; Fairen-Jimenez, David. Synthetic Route of C11H9N3O. The article was titled 《Structure-directing factors when introducing hydrogen bond functionality to metal-organic frameworks》. The information in the text is summarized as follows:
The introduction of H-bond donor/acceptor functionality into metal-organic frameworks (MOFs) can have a beneficial effect on their mol. recognition, uptake selectivity and catalytic properties. The changes in ligand geometry induced by incorporation of functional groups may also affect the topol. and composition of the resultant MOFs. Herein, the authors present a comprehensive study of functional group incorporation into MOFs, linked by either Zn2+ paddlewheel units or monomeric Zn2+ corners, which exhibit pcu and dia topol., resp. Crystallog. anal. shows that amide groups can be easily incorporated into isoreticular pcu pillared-MOFs, while integration of urea units results in materials with dia topol. Mol. simulations allow the examination of hypothetical structures with differing constitutions and topologies, and highlight the influence of the urea units in generating the exptl. observed topologies. Noncovalent interactions between independent nets may be significant structure-directing influences, a finding which has great implications for the design of MOFs containing more complex functional groups. The experimental process involved the reaction of N-(Pyridin-4-yl)isonicotinamide(cas: 64479-78-3Synthetic Route of C11H9N3O)
N-(Pyridin-4-yl)isonicotinamide(cas: 64479-78-3) belongs to amides. The solubilities of amides and esters are roughly comparable. Typically amides are less soluble than comparable amines and carboxylic acids since these compounds can both donate and accept hydrogen bonds.Synthetic Route of C11H9N3O
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics