SDS of cas: 70-55-3In 2021 ,《Highly Selective and Catalytic C-N Bond Cleavage of Tertiary Sulfonamides: Scope and Mechanistic Insight》 was published in ACS Omega. The article was written by Bhattacharya, Aditya; Shukla, Pushpendra mani; Maji, Biswajit. The article contains the following contents:
A highly chemoselective C-N bond cleavage reaction of tertiary sulfonamides RN(CH2R1)S(O)2R2 (R = Ph, 3-chlorophenyl, 3,4-dimethoxyphenyl, etc.; R1 = 4-methoxyphenyl, 3,4-dimethoxyphenyl, 2-phenylethenyl, etc.; R2 = 4-methylphenyl, naphthalen-1-yl, 4-nitrophenyl, etc.) in the presence of catalytic Bi(OTf)3 is presented. A wide range of sulfonamide substrates smoothly furnished the corresponding C-N bond cleavage products RNHS(O)2R2 in good to excellent yields. Great efforts have been made to obtain insights into the reaction mechanism based on a series of control experiments and mass spectroscopy. In addition to this study using 4-Methylbenzenesulfonamide, there are many other studies that have used 4-Methylbenzenesulfonamide(cas: 70-55-3SDS of cas: 70-55-3) was used in this study.
4-Methylbenzenesulfonamide(cas: 70-55-3) belongs to anime. In organic chemistry, amines are compounds and functional groups that contain a basic nitrogen atom with a lone pair. Amines are formally derivatives of ammonia (NH3), wherein one or more hydrogen atoms have been replaced by a substituent such as an alkyl or aryl group (these may respectively be called alkylamines and arylamines; amines in which both types of substituent are attached to one nitrogen atom may be called alkylarylamines).SDS of cas: 70-55-3
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics