Jia, Yibo; Li, Lin; Duan, Lili; Li, Yue-Ming published the artcile< The aza-Prins Cyclization of Unfunctionalized Olefins Promoted by NHC-Cu Complex and ZrCl4>, Related Products of 6961-82-6, the main research area is piperidine preparation diastereoselective zirconium tetrachloride NHC copper catalyst; homoallylic amine aldehyde aza Prins cyclization.
The aza-Prins cyclization reaction catalyzed by ZrCl4 and NHC (N-heterocyclic carbene) metal complexes is firstly reported. NHC-copper complexes as promoter and ZrCl4 as chloride source are utilized under a mild condition, where homoallylic amines and aldehydes are successfully converted to piperidine derivatives in satisfactory yields and diastereoselectivity.
Applied Organometallic Chemistry published new progress about Aldehydes Role: RCT (Reactant), RACT (Reactant or Reagent). 6961-82-6 belongs to class amides-buliding-blocks, and the molecular formula is C6H6ClNO2S, Related Products of 6961-82-6.
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics