《Asymmetric construction of alkaloids by employing a key ω-transaminase cascade》 was written by Taday, Freya; Ryan, James; Argent, Stephen P.; Caprio, Vittorio; Macia, Beatriz; O’Reilly, Elaine. Name: N-Methoxy-N-methylacetamide And the article was included in Chemistry – A European Journal in 2020. The article conveys some information:
An ω-transaminase-triggered intramol. aza-Michael reaction has been employed for the preparation of cyclic β-enaminones in good yield and excellent enantio- and diastereoselectivity, starting from easily accessible prochiral ketoynones and com. available enzymes. The powerful thermodn. driving force associated with the spontaneous aza-Michael reaction effectively displaces the transaminase reaction equilibrium towards product formation, using only two equivalent of isopropylamine. To demonstrate the potential of this methodol., this biocatalytic aza-Michael step was combined with annulation chem., affording unique stereo-defined fused alkaloid architectures. In the part of experimental materials, we found many familiar compounds, such as N-Methoxy-N-methylacetamide(cas: 78191-00-1Name: N-Methoxy-N-methylacetamide)
N-Methoxy-N-methylacetamide(cas: 78191-00-1) belongs to anime. Examples of direct uses of amines and their salts are as corrosion inhibitors in boilers and in lubricating oils (morpholine), as antioxidants for rubber and roofing asphalt (diarylamines), as stabilizers for cellulose nitrate explosives (diphenylamine), as protectants against damage from gamma radiation (diarylamines), as developers in photography (aromatic diamines), as flotation agents in mining, as anticling and waterproofing agents for textiles, as fabric softeners, in paper coating, and for solubilizing herbicides.Name: N-Methoxy-N-methylacetamide
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics