《Structural Diversity in Multinuclear PdII Assemblies that Show Low-Humidity Proton Conduction》 was published in Chemistry – A European Journal in 2014. These research results belong to Samanta, Dipak; Mukherjee, Partha Sarathi. SDS of cas: 64479-78-3 The article mentions the following:
Systematic study on synergetic effects of geometry, length, denticity, and asymmetry of donors was performed through the formation of uncommon PdII aggregates by employing the donor in a multicomponent self-assembly of a cis-blocked 90° PdII acceptor and a tetratopic donor. Some of these assemblies represent the 1st examples of these types of structures, and their formation is not anticipated by only taking the geometry of the donor and the acceptor building units into account. Anal. of the crystal packing of the x-ray structure revealed several H bonds between the counteranions (NO3-) and H2O mols. (O-H···O=N). Also, H-bonded 3-dimensional-networks of H2O are present in the mol. pockets, which show H2O-adsorption properties with some variation in H2O affinity. These complexes exhibit proton conductivity (1.87 × 10-5-6.52 × 10-4 Scm-1) at 296 K and low relative humidity (∼46 %) with activation energies of 0.29-0.46 eV. Also, the conductivities further increase with the enhancement of humidity. The ability of these assemblies to exhibit p-conducting properties under low-humidity conditions makes these materials highly appealing as electrolytes in batteries and in fuel-cell applications. The experimental part of the paper was very detailed, including the reaction process of N-(Pyridin-4-yl)isonicotinamide(cas: 64479-78-3SDS of cas: 64479-78-3)
N-(Pyridin-4-yl)isonicotinamide(cas: 64479-78-3) belongs to amides.SDS of cas: 64479-78-3 Amides include many other important biological compounds, as well as many drugs like paracetamol, penicillin and LSD. Low-molecular-weight amides, such as dimethylformamide, are common solvents.
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics