Zheng, Long-Sheng; Ferard, Charlene; Phansavath, Phannarath; Ratovelomanana-Vidal, Virginie published the artcile< Rhodium-mediated asymmetric transfer hydrogenation: a diastereo- and enantioselective synthesis of syn-α-amido β-hydroxy esters>, Related Products of 1192620-83-9, the main research area is syn alpha amido beta hydroxy ester preparation enantioselective; benzoylamido keto ester hydrogenation rhodium catalyst.
The preparation of syn α-benzoylamido β-hydroxy esters through asym. transfer hydrogenation (ATH) with a tethered Rh(III)-DPEN complex via dynamic kinetic resolution (DKR) has been developed for the first time starting from α-benzoylamido β-keto esters. A variety of α-benzoylamido β-keto esters were converted under mild conditions into the corresponding syn α-benzoylamino β-hydroxy esters with high yields (up to 98%) and diastereomeric ratios (up to >99 : 1 dr) as well as excellent enantioselectivities (up to >99% ee).
Chemical Communications (Cambridge, United Kingdom) published new progress about Enantioselective synthesis. 1192620-83-9 belongs to class amides-buliding-blocks, and the molecular formula is C30H31ClN2O2RuS, Related Products of 1192620-83-9.
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics