Vyas, Vijyesh K.; Clarkson, Guy J.; Wills, Martin published the artcile< Enantioselective Synthesis of Bicyclopentane-Containing Alcohols via Asymmetric Transfer Hydrogenation>, Quality Control of 1192620-83-9, the main research area is oxomethyl bicyclopentane enantioselective transfer hydrogenation; hydroxymethyl cyclopentane preparation.
Compounds a containing bicyclo[1.1.1]pentane (BCP) adjacent to a chiral center was prepared with high enantiomeric excess through asym. transfer hydrogenation (ATH) of adjacent ketones. In the reduction step, the BCP occupies the position distant from the η6-arene of the catalyst. The reduction was applied to the synthesis of a BCP analog of the antihistamine drug neobenodine.
Organic Letters published new progress about Alcohols Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 1192620-83-9 belongs to class amides-buliding-blocks, and the molecular formula is C30H31ClN2O2RuS, Quality Control of 1192620-83-9.
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics