《The chemistry of N-substituted benzotriazoles. Part 20. Mono-N-tert-butylation of aromatic and heteroaromatic amines》 was published in Journal of the Chemical Society in 1989. These research results belong to Katritzky, Alan R.; Vanden Eynde, Jean Jacques. Related Products of 70298-88-3 The article mentions the following:
Adducts R1CH(1-benzotriazolyl)NHR2, (R1 = Pr, CHMe2, CMe3, R2 = 2-, 3-pyridyl, Ph, 4-methyl-2-pyridyl, 5-chloro-2-pyridyl, 3-ClC6H4, 3-, 4-O2NC6H4), readily available from aldehydes, primary aromatic or heteroaromatic amines, and benzotriazole are converted by H2O2-SeO2 into mixtures of R1CONHR2 and HCONR1R2 in proportions which depend rationally on the nature of the R1 group. For R1 = CMe3, the formamide Me3CNR2CHO is formed in satisfactory yields, thus enabling the title reaction to be achieved. After reading the article, we found that the author used 2,2-Dimehtyl-N-pyridin-3-yl-propionamide(cas: 70298-88-3Related Products of 70298-88-3)
2,2-Dimehtyl-N-pyridin-3-yl-propionamide(cas: 70298-88-3) belongs to anime.Typically the presence of an amine functional group is deduced by a combination of techniques, including mass spectrometry as well as NMR and IR spectroscopies. 1H NMR signals for amines disappear upon treatment of the sample with D2O. In their infrared spectrum primary amines exhibit two N-H bands, whereas secondary amines exhibit only one.Related Products of 70298-88-3
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics