Jolley, Katherine E.; Zanotti-Gerosa, Antonio; Hancock, Fred; Dyke, Alan; Grainger, Damian M.; Medlock, Jonathan A.; Nedden, Hans G.; Le Paih, Jacques J. M.; Roseblade, Stephen J.; Seger, Andreas; Sivakumar, Vilvanathan; Prokes, Ivan; Morris, David J.; Wills, Martin published the artcile< Application of Tethered Ruthenium Catalysts to Asymmetric Hydrogenation of Ketones, and the Selective Hydrogenation of Aldehydes>, Quality Control of 1192620-83-9, the main research area is tethered ruthenium catalyst preparation asym hydrogenation ketone aldehyde; sulfonyldiaminoalkyl ruthenium tethered preparation catalyst asym hydrogenation aldehyde ketone.
An improved method for the synthesis of tethered ruthenium(II) complexes of monosulfonylated diamines is described, together with their application to the hydrogenation of ketones and aldehydes. The complexes were applied directly, in their chloride form, to asym. ketone hydrogenation, to give products in excess of 99% ee in the best cases, using 30 bar of hydrogen at 60°, and to the selective reduction of aldehydes over other functional groups.
Advanced Synthesis & Catalysis published new progress about Aldehydes Role: RCT (Reactant), RACT (Reactant or Reagent). 1192620-83-9 belongs to class amides-buliding-blocks, and the molecular formula is C30H31ClN2O2RuS, Quality Control of 1192620-83-9.
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics