Soni, Rina; Collinson, John-Michael; Clarkson, Guy C.; Wills, Martin published the artcile< An Unexpected Directing Effect in the Asymmetric Transfer Hydrogenation of α,α-Disubstituted Ketones>, Name: Chloro[N-[(1R,2R)-1,2-diphenyl-2-[[3-(η6-phenyl)propyl]amino-κN]ethyl]-4-methylbenzenesulfonamidato-κN]ruthenium, the main research area is unexpected directing asym transfer hydrogenation disubstituted ketone crystallog.
α,α-Disubstituted ketones containing an aromatic ring or alkene are reduced in high enantiomeric excess using an asym. transfer hydrogenation catalyst. The sense of reduction indicates that the unsaturated region of the ketone adopts a position adjacent to the Ru-bound η6-arene ring in the reduction transition state.
Organic Letters published new progress about Aryl ketones Role: PEP (Physical, Engineering or Chemical Process), RCT (Reactant), PROC (Process), RACT (Reactant or Reagent). 1192620-83-9 belongs to class amides-buliding-blocks, and the molecular formula is C30H31ClN2O2RuS, Name: Chloro[N-[(1R,2R)-1,2-diphenyl-2-[[3-(η6-phenyl)propyl]amino-κN]ethyl]-4-methylbenzenesulfonamidato-κN]ruthenium.
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics