Ma, Tao; Hua, Jiawei; Bian, Mixue; Qin, Hong; Lin, Xinxin; Yang, Xiaobing; Liu, Chengkou; Yang, Zhao; Fang, Zheng; Guo, Kai published the artcile< Visible light-promoted aerobic oxidative cleavage and cyclization of olefins to access 3-hydroxy-isoindolinones>, Related Products of 6961-82-6, the main research area is alkenylbenzamide iron catalyst photochem regioselective aerobic oxidative cleavage heterocyclization; hydroxy isoindolinone preparation green chem.
A convenient and environmentally friendly synthetic route from 2-vinylbenzimides to 3-hydroxy-isoindolinones through visible light-promoted transformations via iron/disulfide catalysis and mol. oxygen oxidation was developed. A range of 3-hydroxy-isoindolinones were obtained in moderate to good yields, which exhibited excellent functional group compatibility and broad substrate scope. Further mechanistic investigations proved that dioxetane might be a key intermediate being involved in the reaction.
Organic Chemistry Frontiers published new progress about Amines Role: PRP (Properties), RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 6961-82-6 belongs to class amides-buliding-blocks, and the molecular formula is C6H6ClNO2S, Related Products of 6961-82-6.
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics