In 2016,Kawaguchi, Yasuaki; Yasuda, Shigeo; Mukai, Chisato published 《Construction of Hexahydrophenanthrenes By Rhodium(I)-Catalyzed Cycloisomerization of Benzylallene-Substituted Internal Alkynes through C-H Activation》.Angewandte Chemie, International Edition published the findings.HPLC of Formula: 78191-00-1 The information in the text is summarized as follows:
The treatment of benzylallene-substituted internal alkynes with [RhCl(CO)2]2 effects a novel cycloisomerization by C(sp2)-H bond activation to produce hexahydrophenanthrene derivatives The reaction likely proceeds through consecutive formation of a rhodabicyclo[4.3.0] intermediate, σ-bond metathesis between the C(sp2)-H bond on the benzene ring and the C(sp2)-RhIII bond, and isomerization between three σ-, π-, and σ-allylrhodium(III) species, which was proposed based on experiments with deuterated substrates. In addition to this study using N-Methoxy-N-methylacetamide, there are many other studies that have used N-Methoxy-N-methylacetamide(cas: 78191-00-1HPLC of Formula: 78191-00-1) was used in this study.
N-Methoxy-N-methylacetamide(cas: 78191-00-1) belongs to anime. Examples of direct uses of amines and their salts are as corrosion inhibitors in boilers and in lubricating oils (morpholine), as antioxidants for rubber and roofing asphalt (diarylamines), as stabilizers for cellulose nitrate explosives (diphenylamine), as protectants against damage from gamma radiation (diarylamines), as developers in photography (aromatic diamines), as flotation agents in mining, as anticling and waterproofing agents for textiles, as fabric softeners, in paper coating, and for solubilizing herbicides.HPLC of Formula: 78191-00-1
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics