Hodgkinson, Roy; Jurcik, Vaclav; Nedden, Hans; Blackaby, Andrew; Wills, Martin published the artcile< An alternative route to tethered Ru(II) transfer hydrogenation catalysts>, Synthetic Route of 1192620-83-9, the main research area is ruthenium arene tethered preparation transfer hydrogenation catalyst ketone aldehyde.
A new route towards a series of tethered η6-arene/Ru(II) catalysts for use in the transfer and pressure hydrogenation of ketones and aldehydes to alcs. is reported. The route proceeds through the formation of an amide from the diamine precursor, followed by reduction, rather than the direct alkylation of the diamine. This has the advantage that dialkylation of the amine is avoided during the synthesis. Through this new route, both racemic and enantiomerically-pure η6-arene/Ru(II) tethered catalysts can be prepared in high yield.
Tetrahedron Letters published new progress about Alcohols Role: SPN (Synthetic Preparation), PREP (Preparation). 1192620-83-9 belongs to class amides-buliding-blocks, and the molecular formula is C30H31ClN2O2RuS, Synthetic Route of 1192620-83-9.
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics