Zhuang, Xiaohui; Ling, Lan; Wang, Yingying; Li, Bingqian; Sun, Bin; Su, Weike; Jin, Can published the artcile< Photoinduced Cascade C-N/C=O Bond Formation from Bromodifluoroalkyl Reagents, Amines, and H2O via a Triple-Cleavage Process>, SDS of cas: 6280-57-5, the main research area is unsym oxalamide derivative green preparation; bromodifluoroalkyl reagent amine water cascade bond formation photocatalyst.
A green, sustainable, and straightforward method for synthesis of unsym. oxalamides RC(O)NR1R2 [R = C(O)NHPh, C(O)NH-4-BrC6H4, C(O)Ph, etc.; R1 = Me, Et, nPr, etc.; R2 = Me, Et, nPr, etc.; R1R2 = pyrrolidin-1-yl, morpholin-4-yl, cyclohex-1-yl] via photoinduced C-N/C=O bonds formation of bromodifluoroacetamide, amine and H2O through proceeding triple cleavage process was developed. In addition, this approach also gave an access to build the known bioactive compounds, and a feasible reaction mechanism was proposed. Moreover, the advantages of this transformation, including mild reaction conditions, broad substrate scope and operational simplicity, made this protocol attractive for further applications.
Organic Letters published new progress about Acetamides Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation) (bromodifluoro-). 6280-57-5 belongs to class amides-buliding-blocks, and the molecular formula is C17H35NO, SDS of cas: 6280-57-5.
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics