Zheng, Ye; Wills, Martin published the artcile< Asymmetric transfer hydrogenation of boronic acid pinacol ester (Bpin)-containing acetophenones>, Related Products of 1192620-83-9, the main research area is boronic acid pinacol ester acetophenone enantioselective transfer hydrogenation; hydroxyethylphenyl boronic acid pinacol ester preparation haloarene palladium coupling; aryl phenylethanol preparation.
A series of Bpin-containing acetophenone derivatives were reduced by asym. transfer hydrogenation (ATH), using Noyori-Ikariya catalysts, with formic acid/triethylamine, to alcs. in high ee when the Bpin is in the para- or meta-position. Substrates containing ortho-Bpin groups were reduced in lower ee, with formation of a cyclic boron-containing group. The products were converted to substituted derivatives using Pd-catalyzed coupling reactions. The results represent the first examples of ATH of Bpin-containing ketones.
Organic & Biomolecular Chemistry published new progress about Aromatic alcohols Role: SPN (Synthetic Preparation), PREP (Preparation). 1192620-83-9 belongs to class amides-buliding-blocks, and the molecular formula is C30H31ClN2O2RuS, Related Products of 1192620-83-9.
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics