Vats, Bal Govind; Gamare, Jayashree S.; Kannan, S.; Pius, I. C.; Noronha, D. M.; Kumar, M. published the artcile< Synthesis, structural and extraction studies of new bifunctional ligand with uranium>, Related Products of 5326-82-9, the main research area is crystal structure uranyl isobutylcarbamoylthio pyridyloxide; uranyl alkylcarbamoylthio pyridyloxide preparation; actinide solvent extraction alkylcarbamoylthio pyridyloxide.
A new bifunctional ligand system (N,N-dialkyl carbamoyl Me) (2-pyridyl-N-Oxide) sulfide C5H4NOSCH2CONR2, (R = isopropyl (L1), isobutyl (L2) and Bu (L3) and octyl (L4)) were synthesized. The coordination chem. of this ligand system with UO2(NO3)2·6H2O was studied. All the ligands and complexes were characterized by CHN, IR and NMR techniques. Single crystal x-ray study of 2 shows that the U atom is surrounded by eight O atoms in a hexagonal-bi-pyramidal geometry. The ligand is bonded to metal through carbamoyl and N-oxide groups in a chelating fashion. Thermogravimetric studies of the complexes shows that the ligands are completely incinerable. Extraction studies of the actinides with ligand L4 show that this new bifunctional ligand has very good distribution ratio (D) values for tetravalent and hexavalent actinides ions from HNO3 medium.
Inorganica Chimica Acta published new progress about Actinides Role: PEP (Physical, Engineering or Chemical Process), PROC (Process). 5326-82-9 belongs to class amides-buliding-blocks, and the molecular formula is C10H20ClNO, Related Products of 5326-82-9.
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics