Sharma, Shikha; Ghosh, Sunil K.; Kumar, Mukesh; Sharma, Joti N. published the artcile< Synthesis and X-ray crystallographic characterization of two different inorganic-organic hybrid isopolyoxomolybdates with α-dipropylammonium N,N-diisobutylacetamide by varying reaction conditions>, Recommanded Product: 2-Chloro-N,N-diisobutylacetamide, the main research area is propylammonium diisobutylacetamide polyoxomolybdate complex preparation crystal structure.
Two new polyoxomolybdate based inorganic-organic hybrid compounds were obtained from same ammonium ion ligand 1 and molybdate source just by altering reaction conditions. The new hybrid polyoxomolybdate complexes (LH)2[Mo6O19] 3 and (LH)4[Mo8O26](MeCN)2 4 have distinct structural features revealed by x-ray crystallog. studies. The complex 3 contains two ammonium ligands to balance the charge on hexamolybdate dianion. The most striking feature of (LH)2[Mo6O19] is the presence of inter-ligand hydrogen bonding (N-H···O:C) between two ligands arranged in an antiparallel fashion that favors the formation of a net like structure which embeds the Mo6O19 dianion. The complex 4 contains four ammonium ligands to balance the charge on β-octamolybdate tetraanion. Complex 4 exhibits strong hydrogen-bonding interactions between ammonium ligand and octamolybdate anion (N-H···O-Mo) and no inter-ligand H-bonding interaction. The different structural features of hybrid compounds 3 and 4 suggest that different polyoxomolybdate clusters play a key role in the process of assembling of ligands.
Polyhedron published new progress about Crystal structure. 5326-82-9 belongs to class amides-buliding-blocks, and the molecular formula is C10H20ClNO, Recommanded Product: 2-Chloro-N,N-diisobutylacetamide.
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics