Recently I am researching about MEINWALD REARRANGEMENT REACTIONS; PROMOTED REARRANGEMENT; SELECTIVE SYNTHESIS; CONVERSION; CYCLOPROPANES; CARBONYLATION; COMPLEXES; OXIDATION; ALDEHYDES, Saw an article supported by the Spanish Ministry of Economy, Industry and Competitiveness (MINECO) through the Centres of Excellence Severo Ochoa award [CTQ2017-87840-P, CTQ2017-87889-P]; IRB Barcelona through the CERCA Programme of the Catalan Government; MINECO; UAB. Application In Synthesis of Diphenylmethanamine. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Cabre, A; Cabezas-Gimenez, J; Sciortino, G; Ujaque, G; Verdaguer, X; Lledos, A; Riera, A. The CAS is 91-00-9. Through research, I have a further understanding and discovery of Diphenylmethanamine
The isomerization of epoxides to aldehydes using the readily available Crabtree’s reagent is described. The aldehydes were transformed into synthetically useful amines by a one-pot reductive amination using pyrrolidine as imine-formation catalyst. The reactions worked with low catalyst loadings in very mild conditions. The procedure is operationally simple and tolerates a wide range of functional groups. A DFT study of its mechanism is presented showing that the isomerization takes place via an iridium hydride mechanism with a low energy barrier, in agreement with the mild reaction conditions.
Application In Synthesis of Diphenylmethanamine. Bye, fridends, I hope you can learn more about C13H13N, If you have any questions, you can browse other blog as well. See you lster.
Reference:
Amide – Wikipedia,
,Amide – an overview | ScienceDirect Topics