Quality Control of Diphenylmethanamine. Wang, Y; Cao, XY; Zhao, LY; Pi, C; Ji, JF; Cui, XL; Wu, YJ in [Wang, Yong; Pi, Chao; Cui, Xiuling; Wu, Yangjie] Zhengzhou Univ, Key Lab Appl Chem Henan Univ, Green Catalysis Ctr, Henan Key Lab Chem Biol & Organ Chem, Zhengzhou 450052, Peoples R China; [Wang, Yong; Pi, Chao; Cui, Xiuling; Wu, Yangjie] Zhengzhou Univ, Coll Chem, Zhengzhou 450052, Peoples R China; [Cao, Xinyi; Zhao, Leyao; Ji, Jingfei] Zhengzhou Univ, Int Coll, Zhengzhou 450052, Peoples R China published Generalized Chemoselective Transfer Hydrogenation/Hydrodeuteration in 2020, Cited 156. The Name is Diphenylmethanamine. Through research, I have a further understanding and discovery of 91-00-9.
A generalized, simple and efficient transfer hydrogenation of unsaturated bonds has been developed using HBP in and various proton reagents as hydrogen sources. The substrates, including alkenes, alkynes, aromatic heterocycles, aldehydes, ketones, imines, azo, nitro, epoxy and nitrile compounds, are all applied to this catalytic system. Various groups, which cannot survive under the Pd/C/H-2 combination, are tolerated. The activity of the reactants was studied and the trends are as follows:styrene>diphenylmethanimine>benzaldehyde>azobenzene>nitrobenzene>quinoline>acetophenone>benzonitrile. Substrates bearing two or more different unsaturated bonds were also investigated and transfer hydrogenation occurred with excellent chemoselectivity. Nano-palladium catalystin situgenerated from Pd(OAc)(2) and HBP in extremely improved the TH efficiency. Furthermore, chemoselective anti-Markovnikov hydrodeuteration of terminal aromatic olefins was achieved using D2O and HBP in via in situ HD generation and discrimination.
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Reference:
Amide – Wikipedia,
,Amide – an overview | ScienceDirect Topics