An article Selective Synthesis of Secondary Amines from Nitriles by a User-Friendly Cobalt Catalyst WOS:000483835300004 published article about TRANSFER HYDROGENATION; AROMATIC NITRILES; MILD; COMPLEXES; INDOLES; IMINES; (DE)HYDROGENATION; ALKYNYLATION; ALKYLATION; ALDEHYDES in Dr Homi Bhabha Rd, Pune 411008, Maharashtra, India; [Sharma, Dipesh M.; Punji, Benudhar] NCL, CSIR, Div Chem Engn, Organometall Synth & Catalysis Grp, Pune 411008, Maharashtra, India; [Sharma, Dipesh M.; Punji, Benudhar] NCL, CSIR, Acad Sci & Innovat Res AcSIR, Pune 411008, Maharashtra, India in 2019.0, Cited 57.0. SDS of cas: 91-00-9. The Name is Diphenylmethanamine. Through research, I have a further understanding and discovery of 91-00-9
Selective hydrogenation/reductive amination of nitriles to secondary amines catalyzed by an inexpensive and user-friendly cobalt complex, (Xantphos)CoCl2, is reported. The use of (Xantphos)CoCl2 and ammonia borane (NH3-BH3) combination affords the selective reduction of nitriles to symmetrical secondary amines, whereas the employment of (Xantphos)CoCl2 and dimethylamine borane (Me2NH-BH3) along with external amines produce unsymmetrical secondary amines and tertiary amines. The general applicability of this methodology is demonstrated by the synthesis of 43 symmetrical and unsymmetrical secondary and tertiary amines bearing diverse functionalities.
About Diphenylmethanamine, If you have any questions, you can contact Sharma, DM; Punji, B or concate me.. SDS of cas: 91-00-9
Reference:
Amide – Wikipedia,
,Amide – an overview | ScienceDirect Topics