A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, SDS of cas: 6292-59-7, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 6292-59-7, Name is 4-(tert-Butyl)benzenesulfonamide, molecular formula is C10H15NO2S. In an article, author is Guo, Xuliang,once mentioned of 6292-59-7.
The first total synthesis of chondrochloren A is accomplished using a 1,2-metallate rearrangement addition as an alternative for the Nozaki-Hiyama-Kishi reaction. This transformation also avoids the inherent challenges of this polyketide segment and provides a new, unprecedented strategy to assemble polyketidal frameworks. The formation of the Z-enamide is accomplished using a Z-selective cross coupling of the corresponding amide to a Z-vinyl bromide.
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Reference:
Amide – Wikipedia,
,Amide – an overview | ScienceDirect Topics