Let’s face it, organic chemistry can seem difficult to learn. Especially from a beginner’s point of view. Like 109425-51-6, Name is Fmoc-His(Trt)-OH. In a document, author is Yang, Hai-Long, introducing its new discovery. Application In Synthesis of Fmoc-His(Trt)-OH.
Csp(3)-H oxidation of benzylic methylene compounds is an established strategy for the synthesis of aromatic ketones, esters, and amides. The need for more sustainable oxidizers has encouraged researchers to explore the use of molecular oxygen. In particular, homogeneous metal-catalyzed aerobic oxidation of benzylic methylenes has attracted much attention. This account summarizes the development of this oxidative strategy in the last two decades, examining key factors such as reaction yields, substrate: catalyst ratio, substrate scope, selectivity over other oxidation byproducts, and reaction conditions including solvents and temperature. Finally, several mechanistic proposals to explain the observed results will be discussed.
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Reference:
Amide – Wikipedia,
,Amide – an overview | ScienceDirect Topics