Chemistry is an experimental science, Quality Control of H-Glu(OtBu)-OtBu.HCl, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 32677-01-3, Name is H-Glu(OtBu)-OtBu.HCl, molecular formula is C13H26ClNO4, belongs to amides-buliding-blocks compound. In a document, author is Deng, Xi-Le.
A series of molybdenum pincer complexes has been shown for the first time to be active in the catalytic hydrogenation of amides. Among the tested catalysts, Mo-1a proved to be particularly well suited for the selective C-N hydrogenolysis of N-methylated formanilides. Notably, high chemoselectivity was observed in the presence of certain reducible groups including even other amides. The general catalytic performance as well as selectivity issues could be rationalized taking an anionic Mo(0) as the active species. The interplay between the amide CO reduction and the catalyst poisoning by primary amides accounts for the selective hydrogenation of N-methylated formanilides. The catalyst resting state was found to be a Mo-alkoxo complex formed by reaction with the alcohol product. This species plays two opposed roles – it facilitates the protolytic cleavage of the C-N bond but it encumbers the activation of hydrogen.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law. In my other articles, you can also check out more blogs about 32677-01-3. Quality Control of H-Glu(OtBu)-OtBu.HCl.
Reference:
Amide – Wikipedia,
,Amide – an overview | ScienceDirect Topics