Chemistry is the experimental and theoretical study of materials on their properties at both the macroscopic and microscopic levels. 3184-13-2, Name is H-Orn-OH Hydrochloride, molecular formula is C5H13ClN2O2. In an article, author is Gondi, Sudershan R.,once mentioned of 3184-13-2, Application In Synthesis of H-Orn-OH Hydrochloride.
Binary electrolytes of Li salt in ionic liquid (IL) are interesting systems for battery application. Typical for these systems is a strong Li-anion coordination causing vehicular Li+ transport in negatively charged Li-anion clusters and negative Li+ transference numbers. We investigate the influence of the additives tetrahydrofuran, monoglyme and triglyme on the Li+ migration behavior in 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)amide (EMImTFSA) based mixtures via electrophoretic NMR. When adding coordinating additives, we partly observe a reversal of the lithium migration direction and an electrophoretic drift of the neutral molecule. Using the same O:Li ratio, this effect is strongly depending on the chelating ability of the respective additive. Strongly coordinating additives form a chelate with the Li ion and render its drift velocity and its transference number positive, while the nonchelating additive tetrahydrofuran has a weaker effect on the Li drift. By choice of a suitable additive, it is therefore possible to decompose negatively charged lithium-anion clusters while maintaining ionic liquid-like properties. These findings provide a mechanistic explanation for the beneficial effect of additives on Li+ transport in IL-based battery cells.
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Reference:
Amide – Wikipedia,
,Amide – an overview | ScienceDirect Topics