The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature. 536-90-3, Name is 3-Methoxyaniline, SMILES is NC1=CC=CC(OC)=C1, in an article , author is Jeon, Heeyoung, once mentioned of 536-90-3, Product Details of 536-90-3.
Pillar[5]arenes are a new type of supramolecular hosts constructed from hydroquinone and their derivatives linked by methylene units. Searching new host-guest interaction between pillar[5]arenes and neutral guests are thus great interesting. Here, four neutral guests (AA0, AA2, AA4 and AA6) with both amino and amide groups were prepared from phenol by two steps. The host-guest interactions between perethylated pillar[5]arene (EtP5) and guest molecules were investigated in detail by various technologies, including H-1 NMR, C-13 NMR, 2D NOESY NMR, MS analysis and DFT calculation. We found that the guests (AA4 and AA6) with longer alkyl chain can form a stable inclusion complex with EtP5 through C-H center dot center dot center dot O, N-H center dot center dot center dot O, C-H center dot center dot center dot N and C-H center dot center dot center dot pi interactions while shorter guests (AA0 and AA2) could not. [GRAPHICS] .
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Reference:
Amide – Wikipedia,
,Amide – an overview | ScienceDirect Topics