Chemistry is the experimental and theoretical study of materials on their properties at both the macroscopic and microscopic levels. 112101-81-2, Name is R-5-(2-Aminopropyl)-2-methoxybenzenesulfonamide, molecular formula is C10H16N2O3S. In an article, author is Hassanein, Taha F.,once mentioned of 112101-81-2, HPLC of Formula: https://www.ambeed.com/products/112101-81-2.html.
A transition-metal-catalyzed borrowing hydrogen/hydrogen auto-transfer strategy allows the utilization of feedstock alcohols as an alkylating partner, which avoids the formation of stoichiometric salt waste and enables a direct and benign approach for the construction of C-N and C-C bonds. In this study, a nickel-catalyzed alpha-alkylation of unactivated amides and ester (tert-butyl acetate) is carried out by using primary alcohols under mild conditions. This C-C bond-forming reaction is catalyzed by a new, molecularly defined nickel(II) NNN-pincer complex (0.1-1 mol %) and proceeds through hydrogen auto-transfer, thereby releasing water as the sole byproduct. In addition, N-alkylation of cyclic amides under Ni-catalytic conditions is demonstrated.
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Reference:
Amide – Wikipedia,
,Amide – an overview | ScienceDirect Topics