A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 53075-09-5, Name is N,N,N-Trimethyladamantan-1-aminium hydroxide, molecular formula is C13H25NO. In an article, author is Lai, Holden W. H.,once mentioned of 53075-09-5, Recommanded Product: 53075-09-5.
Photocatalytic amidation and esterification with perfluoroalkyl iodide
The successful generation of perfluoroalkyl radicals (R-f) through photoredox catalysis has inspired us to investigate the preparation of various organofluorine species. In this work, visible light-induced photocatalytic reactions for the preparation of perfluoroalkyl amides and esters from the corresponding amines and alcohols using different types of triplet emitters as photocatalysts have been studied. The effects of the excited-state characteristics and redox potentials of the photocatalysts have been elucidated. Under optimized reaction conditions, these reactions can be performed successfully with different types of amines or alcohols and perfluoroalkyl iodides. Detailed mechanistic studies based on emission quenching experiments have been performed to study the photocatalytic cycles as well as the role of the different reagents. The proposed mechanism has also been examined by DFT calculations.
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