Chemistry is the experimental and theoretical study of materials on their properties at both the macroscopic and microscopic levels. 5704-04-1, Name is 2-((1,3-dihydroxy-2-(hydroxymethyl)propan-2-yl)amino)acetic acid, molecular formula is C6H13NO5. In an article, author is Zhao, Siling,once mentioned of 5704-04-1, Quality Control of 2-((1,3-dihydroxy-2-(hydroxymethyl)propan-2-yl)amino)acetic acid.
Carbonate-Catalyzed Room-Temperature Selective Reduction of Biomass-Derived 5-Hydroxymethylfurfural into 2,5-Bis(hydroxymethyl)furan
Catalytic reduction of 5-hydroxymethylfurfural (HMF), deemed as one of the key bio-based platform compounds, is a very promising pathway for the upgrading of biomass to biofuels and value-added chemicals. Conventional hydrogenation of HMF is mainly conducted over precious metal catalysts with high-pressure hydrogen. Here, a highly active, sustainable, and facile catalytic system composed of K2CO3, Ph2SiH2, and bio-based solvent 2-methyltetrahydrofuran (MTHF) was developed to be efficient for the reduction of HMF. At a low temperature of 25 degrees C, HMF could be completely converted to 2,5-bis(hydroxymethyl)furan (BHMF) in a good yield of 94% after 2 h. Moreover, a plausible reaction mechanism was speculated, where siloxane in situ formed via hydrosilylation was found to be the key species responsible for the high reactivity.
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