Let’s face it, organic chemistry can seem difficult to learn, SDS of cas: 33045-52-2, Especially from a beginner’s point of view. Like 33045-52-2, Name is Methyl 2-methoxy-5-sulfamoylbenzoate, molecular formula is amides-buliding-blocks, belongs to amides-buliding-blocks compound. In a document, author is Kajthunyakarn, Wanassnant, introducing its new discovery.
Direct synthesis of anomeric tetrazolyl iminosugars from sugar-derived lactams
Herein we present the direct asymmetric synthesis of tetrazole-functionalized 1-deoxynojirimycin derivatives from simple sugars via a Schwartz’s reagent-mediated reductive amide functionalization followed by a variant of the Ugi-azide multicomponent reaction. The anomeric configurations of two products were unambiguously confirmed by X-ray analysis. This work also describes examples of interesting further transformations of the title products. Finally, some surprising observations regarding the mechanism of their formation were made.
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