In an article, author is Sarbu, Alexandru, once mentioned the application of 51857-17-1, Formula: C11H24N2O2, Name is N-Boc-1,6-Diaminohexane, molecular formula is C11H24N2O2, molecular weight is 216.3205, MDL number is MFCD00671489, category is amides-buliding-blocks. Now introduce a scientific discovery about this category.
Computational and Experimental Study of Turbo-Organomagnesium Amide Reagents: Cubane Aggregates as Reactive Intermediates in Pummerer Coupling
The dynamic equilibria of organomagnesium reagents are known to be very complex, and the relative reactivity of their components is poorly understood. Herein, a combination of DFT calculations and kinetic experiments is employed to investigate the detailed reaction mechanism of the Pummerer coupling between sulfoxides and turbo-organomagnesium amides. Among the various aggregates studied, unprecedented heterometallic open cubane structures are demonstrated to yield favorable barriers through a concerted anion-anion coupling/ S-O cleavage step. Beyond a structural curiosity, these results introduce open cubane organometallics as key reactive intermediates in turbo-organomagnesium amide mixtures.
If you are interested in 51857-17-1, you can contact me at any time and look forward to more communication. Formula: C11H24N2O2.