One of the major reasons for studying chemical kinetics is to use measurements of the macroscopic properties of a system, such as the rate of change in the concentration of reactants or products with time. 98-10-2, Name is Benzenesulfonamide, formurla is C6H7NO2S. In a document, author is Wang, Lizhen, introducing its new discovery. Formula: C6H7NO2S.
Metal-Free Catalytic Formylation of Amides Using CO2 under Ambient Conditions
This study reports the metal-free formylation of amides using carbon dioxide under ambient conditions. An abnormal N-heterocyclic carbene (aNHC) acts as an efficient catalyst for the formylation of amides in the presence of hydrosilane at room temperature. This methodology enables the formation of a C-N bond and can be utilized in building up core moieties of two natural products having strong larvicidal activity such as alatamide and lansiumamide A. A preliminary mechanistic picture for this transformation has been proposed through isolation of reaction byproduct (confirmed by single crystal X-ray study) as well as by characterizing intermediates with spectroscopy.
I hope this article can help some friends in scientific research. I am very proud of our efforts over the past few months and hope to 98-10-2 help many people in the next few years. Formula: C6H7NO2S.